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International RILEM Conference on Materials, Systems and Structures in Civil Engineering
Conference segment on Service Life of Cement-Based Materials and Structures
22-24 August 2016, Technical University of Denmark, Lyngby, Denmark
Figure 5:
continued
4. Discussion of Test Results
The flexural performances are evaluated in this section by considering mineral admixture
incorporation compared with control specimens. The cement matrix negatively influences the
BF fibre-matrix interface after 7 days. Drop rate in averaged flexural strains is evident (28%)
from 7 days to 28 days [11]. It can be seen in SEM images that the appearance of fibre is no-
longer smooth, and the surface is filled with C-S-H more and more (Fig.6 a,b). Mineral
admixture replacement retards the C-S-H deposits to 28 days and beyond it. In addition, the
drop rate of strains in following curing times decreases as well. In all the experiments, both
BF and GF presented high dimensional stability.
C-S-H densification accelerates in severe wetting-heating durability cycles (Fig.6 c,d) as a
result of ongoing hydration in cement particles. Consequently, a sharp brittle failure mode is
observed even after first cycles. None of BF-NC,S1,S2 series gives rise acceptable
performance in heat-rain cycles possibly due to the humid/warm conditions supporting
hydration process.
In BF-NC,S1, S2 series, it is interesting that remaining strain capacity after 100
th
freeze-thaw
cycles is in the range of 0.4-0.6%. Brittle behaviour of BF-specimens in the heat-rain cycles is
not observed in freeze-thaw cycles (Fig.6 e,f). The structure of matrix and fibre ductility were
improved with mineral admixtures.
It is interesting that debonding and degradation in matrix are monitored in GF-S2 series after
freeze-thaw cycles, quite smooth surface of fibre and trace of debonding are observed in the
SEM images (Fig.6 g,h). In heat-rain cycles, 20% increase in strain capacity is under
consideration, however this enhancement may be a sign of partial debonding as well.
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International RILEM Conference on Materials, Systems and Structures in Civil Engineering
Conference segment on Service Life of Cement-Based Materials and Structures
22-24 August 2016, Technical University of Denmark, Lyngby, Denmark
(a)
(b) (c) (d)
(e) (f) (g) (h)
Figure 6 : Schematical strain comparisons of BF- cementitious composites under flexure test
and SEM micrographs from (a) BF, 7 days, 100% cement; (b) BF, 28 days, 100% cement;
(c),(d) BF after heat-rain 50
th
cycles, 100% cement; (e),(f) BF surface and cementitious matrix
in BF-S1 after 100
th
freeze-thaw cycle; (g),(h) cementitious matrix and trace of fibre
debonding in GF-S2 after 100
th
freeze-thaw cycle .
5. Conclusions
In
this study, the variations of flexural capacities at 3,7,28,56,90 and 120 days as well as at
durability conditions of basalt fibre cementitious composites are addressed. It is aimed to
improve BF-matrix interface by mineral additives and to compare GF-ones. The findings
from this study are given below:
100% cement use gives rise to significant reductions in flexural capacity after 7 days in BF-
cementitious composites. Deposition of C-S-H and CH changes and densifies the fibre-matrix
interface, and the failure mode leads to brittle behaviour due to overbonding. Any sign of
C S H
Fibre
Trace
of fibre
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International RILEM Conference on Materials, Systems and Structures in Civil Engineering
Conference segment on Service Life of Cement-Based Materials and Structures
22-24 August 2016, Technical University of Denmark, Lyngby, Denmark
alkali attack due to CH or lamination due to C-S-H deposits are not observed on the surface of
basalt fibres.
By using sustainable natural or byproduct puzzolanic admixtures as from local sources, e.g
nano clay and high-volume slag, strength and strain retention were provided up to 56 days,
afterwards the drop trend especially in strains substantially slow down compared to 100%
cement case. C-S-H accumulation on fibre surface induced embrittlement decreased
significantly.
15% nano-clay use enhanced 28-day strength over 100% cement ones in BF-specimens, and
decreased the strain reduction from 7 to 28 days. High slag ratios (50%, 80%) especially
decreased the flexural strengths and strains of BF-ones higher than GF-ones. However the rate
in strain reduction at the later curing periods decreased significantly.
It is interesting that 80% slag ratio affected fibre-matrix bond mechanism in GF-ones, the
fibre debonding accompanies to matrix degradation under freeze-thaw conditions. This
situation is partially observed in heat-rain test.
Further research is necessary to solve the brittleness of BF-cementitious composites during
heat-rain test. Heating and wet conditions accelerate the hydration and lead brittle behaviour.
Any degradation in matrix or debonding is not under consideration compared to GF-ones.
New matrix modifications and maybe another surface treatment for basalt fibres may be
experienced.
The freeze-thaw resistance of BRC were enhanced through the mineral admixtures. Flexural
strains in the range of 0.4-0.6% become possible. Thus, a step to toward ductile failure mode
was succeeded. This research will proceed with further experiments on this subject.
Acknowledgement
The experiments in this study were carried out in Fibrobeton Inc. Material, employer and
equipment support of those firm to this experimental research are greatly appreciated. I’m
also thankful to MSc student Cihan Yolcu for his assistance to compiling of some data and to
Dr.Ali Can Zaman for his attention in SEM micrographs.
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