40
Figure 5-6. MIB concentrations along the Arizona Canal on September 20, 2001, showing a “hotspot” of
MIB production between Highway 87 and Mesa Road.
Figure 5-7. MIB Concentrations along the Arizona on during July 2000, showing “hotspot”
of production
between Squaw Peak and Deer Valley WTP.
0
20
40
60
80
100
120
0
2
4
6
8
10
Distance (miles)
MIB (ng/L)
Deer Valley
Squaw Peak
∆
MIB:
> 60 ng/L
16
th
ST
Central
Northern
19
th
Ave
7
th
ST
0
20
40
60
80
0
5
10
15
20
Distance (miles)
MIB (ng/L)
September 2001
∆
MIB: > 30 ng/L
87 FWY
Mesa
Pima
41
Canal sampling can also confirm the effectiveness of treatment of “hotspots” (Figures 5-8
and 5-9) by demonstrating decreases in MIB/geosmin concentrations following the canal
treatment.
Figure 5-8. Effect of
canal wall brushing on the reduction of MIB concentration. The treated Arizona Canal
section was between Central and 19
th
Avenue (August 2000).
0
10
20
30
40
50
60
70
80
MIB (ng/L)
0
10
20
30
40
50
60
70
80
MIB (ng/L)
Before brushing
After brushing
Central
19
th
Ave
Sampling sites
42
20
30
40
50
60
70
80
0
5
10
15
20
Canal distance (miles)
MIB (ng/L)
20-Sep
4-Oct
Figure 5-9. Effect of canal
treatments (copper addition and canal wall brushing) on MIB production in the
Arizona Canal upstream between Highway 87 and Mesa Drive.
5.3.4 Biocide Coating on Concrete Canal
Coating the concrete-lined canals could serve two benefits: (1) reduce frictional losses
and increase hydraulic capacity of canals, and (2) reduce quantity of biomass attached
to the surface. Two types of products were field-tested. First, a polymeric organic
coating (Alphacoat 454), manufactured by Coating Systems Inc., has an active
ingredient containing quaternary ammonium compounds with a trihydroxy silicone
moiety. This ingredient is water-soluble and exists as a hydrated species. Thus the
biocide is both water-soluble and becomes an insoluble polymer when bonded to a
surface, by the process of evaporation of the water molecule. If there are hydroxy
groups present in the substrate there will be better bonding as in the case of concrete
and masonry. The insoluble long chain polymer (-C
18
H
37
(CH
3
)
2
N
+
CH
2
CH
2
CH
2
Si(OH)
3
Cl-)
imparts water repellency and the ammonium chloride gives the biocidal effectiveness.
Second, a white-colored marine antifouling paint (EP2000) has been used on the hulls of
boats to prevent algae and other marine microorganisms from attaching to the surface of
the boats which reduce the efficiency of the marine vehicles. It was determined that
EP2000 produces hydrogen peroxide on the surface, a mild disinfectant. Excess
hydrogen peroxide can lead to chlorine consumption in water treatment applications, but
was not considered significant at the low levels that may be produced in full-scale
applications. Both coatings reduce surface tension, which would have the effect of
decreasing surface roughness on the canal. Neither product currently has NSF approval
for use in water treatment plants, but approval should be pursued. Based upon field-
tests, a tentative recommendation would be to pursue the use of the antifouling paint.
Before treatment
After treatment
87 FWY
Mesa
Pima
Scottsdale
43
The canal surfaces would need to be cleaned and then coated while the canal walls are
dry. One to two coats of the product would be required. The coating should be applied
from 1 foot above the high water level to a depth of 3 feet below the normal water level.
It is currently unclear how frequently the coating would have to be reapplied.
5.4 WATER TREATMENT PLANT SOURCE SWITCHING
5.4.1 Rationale
Reduction of T&O problems can also be accomplished by source switching. As used
here, the term source switching means switching water production
from WTPs receiving
poor quality water to plant(s) receiving better quality water.
Source switching can be useful to the WSD because the five main treatment plants
receive water of varying quality (See Figures 2-1 and 2-2). As noted in Section 2, the
order of MIB concentrations in the inflows of the treatment plants is:
(highest) Deer Valley >> Squaw Peak >> Val Vista >> Union Hills (lowest)
From a standpoint of T&O management, production should be increased at the Union
Hills and Val Vista WTPs and reduced at the Deer Valley WTP, to the extent possible,
during the peak of the T&O season (typically August to October).
5.4.2 Potential for Source Switching
The key factor that must be considered in using source switching is the total production
capacity of the operable WTPs and the total consumer demand. Total operational
production capacity can be managed, to some extent, by conducting repairs at times
other than the peak of the T&O season, so that operational capacity is at a maximum
when source switching is needed.
5.5 CONTROLS WITHIN WATER TREATMENT PLANTS
5.5.1 Prevent In-Plant MIB or Geosmin Production
Algae growth within WTPs pose both an operation problem and potential to form T&O
compounds. Algae “mats” can clog weirs and algae cells of all types reduce filter run
times. Substantial production of T&O compounds has not been observed in City of
Phoenix WTPs, but MIB production within the WTP was observed by the City of Tempe
and City of Chandler. Therefore, it is important to control the growth of algae within
WTPs. The following techniques are recommended with certain qualifying statements: